分类： 物理学 >> 凝聚态:电子结构、电、磁和光学性质 提交时间： 2022-04-30
摘要： Strain engineeringof 2D materials is capable of tuning the electrical and optical properties of the materialswithout introducing additional atoms. However, there are still great challenges in realizing strainingof 2D materials with CMOS compatibility. Here, a method for large-scale ultrafast strain engineering of CVD-grown 2D materials is proposed. We introduce locally non-uniform strains through the cooperative deformation of materials and metal/metal oxide core/shell nanoparticles through cold laser shock. Raman and PL spectrareveal that the tensile strain of MoS2changes and the band gap decreases after laser shock. MD simulations are used to investigate the mechanism of the ultrafast straining of CVD-grown 2D materials. Field effect transistors of CVD MoS2were fabricated, and the performances before and after straining of the same devices are compared. By adjusting the strain level of MoS2, the field effect mobility can be increased from 1.9 cm2V-1s-1 to 44.1 cm2V-1s-1. This is the maximum value of MoS2FETs grown by CVDwith SiO2as dielectric. As an environment-friendly, large-scale and ultra-fast manufacturing method, laser shock provides a universal strategy for large-scale adjustment of 2D materials strain, which will help to promote the manufacturing of 2D nano electronic devices and optoelectronic devices.
分类： 机械工程 >> 机械制造自动化 提交时间： 2022-10-21
摘要： With growing interest in Laser Additive Manufacturing (LAM) of High-entropy alloys (HEAs) during most recent years, compositional elements design and process strategies innovation are primary methods to overcome undesirable microstructures and defects. Here we propose a new approach, a novel real-time laser shock modulation of melt pool (LSMMP) to obtain melt pool modifications for yielding HEAs with desired characteristics. LSMMP utilizes a pulsed laser shocking a liquid melt pool caused by a continuous wave laser, enabling non-destructive and real-time modulations for high-performance HEAs. The numerical simulation reveals the convection mechanism of the melt pool in the LSMMP process, and the intervention of the pulsed laser promotes melt pool flow type to convert the Marangoni effect into a multi-convective ring, which accelerates melt pool flow and inhibits columnar crystal growth. Experimental results show the evolution law of the microstructure in the LSMMP process. The microstructure of CrFeCoNi HEAs undergoes a Columnar-Equiaxed Transition (CET), and higher hardness is obtained. Laser shock is demonstrated to be an effective in-situ modulative tool for controlled additive manufacturing.
分类： 机械工程 >> 机械制造自动化 提交时间： 2022-05-31
摘要： With growing interest in Laser Additive Manufacturing (LAM) of High-entropy alloys (HEAs) during most recent years, the design of compositional elements and process strategies are primary methods to overcome undesirable microstructures and defects. Here we propose a new approach, a novel real-time Laser Shocking of Melt Pool (LSMP), to obtain melt pool modifications for yielding HEAs with desired characteristics. LSMP utilizes a pulsed laser shocking a liquid melt pool caused by a continuous wave laser, enabling non-destructive and real-time modulations for high-performance HEAs. The numerical simulation reveals the convection mechanism of the melt pool in the LSMP process, and the intervention of the pulsed laser promotes melt pool flow type to convert the Marangoni effect into a multi-convective ring, which accelerates melt pool flow and inhibits columnar crystal growth. Experimental results show the evolution law of the microstructure in the LSMP process. The microstructure of CrFeCoNi HEAs undergoes a Columnar-Equiaxed Transition (CET), and higher hardness is obtained. Laser shock is demonstrated to be an effective in-situ modulative tool for controlled additive manufacturing.
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