Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: The chemical inventory of hot Jupiter (HJ) exoplanets atmospheres continue to be observed by various ground and space based instruments in increasing detail and precision. It is expected that some HJs will exhibit strong non-equilibrium chemistry characteristics in their atmospheres, which might be inferred from spectral observations. We aim to model the three dimensional thermochemical non-equilibrium chemistry in the atmospheres of the HJs WASP-39b and HD 189733b. We couple a lightweight, reduced chemical network `mini-chem' that utilises net reaction rate tables to the Exo-FMS General Circulation Model (GCM). We perform GCM models of the exoplanets WASP-39b and HD 189733b as case studies of the coupled mini-chem scheme. The GCM results are then post-processed using the 3D radiative-transfer model gCMCRT to produce transmission and emission spectra to assess the impact of non-equilibrium chemistry on their observable properties. Both simulations show significant departures from chemical equilibrium (CE) due to the dynamical motions of the atmosphere. The spacial distribution of species generally follows closely the dynamical features of the atmosphere rather than the temperature field. Each molecular species exhibits a different quench level in the simulations, also dependent on the latitude of the planet. Major differences are seen in the transmission and emission spectral features between the CE and kinetic models. Our simulations indicate that considering the 3D kinetic chemical structures of HJ atmospheres has an important impact on physical interpretation of observational data. Drawing bulk atmospheric parameters from fitting feature strengths may lead to inaccurate interpretation of chemical conditions in the atmosphere of HJs. Our open source mini-chem module is simple to couple with contemporary HJ GCM models without substantially increasing required computational resources.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: The atmospheres of ultra hot Jupiters (UHJs) are prime targets for the detection of molecules and atoms at both low and high spectral resolution. We study the atmospheres of the UHJs WASP-121b and WASP-189b by performing 3D general circulation models (GCMs) of these planets using high temperature correlated-k opacity schemes with ultra-violet (UV) absorbing species included. The GCM results are then post-processed at low and high spectral resolutions and compared to available data. The high resolution results are cross-correlated with molecular and atomic templates to produce mock molecular detections. Our GCM models produce similar temperature-pressure (T-p) structure trends to previous 1D radiative-convective equilibrium models of UHJs. Furthermore, the inclusion of UV opacities greatly shapes the thermal and dynamical properties of the high-altitude, low-pressure regions of the UHJ atmospheres, with sharp T-p inversions due to the absorption of UV light. This suggests that optical wavelength, high-resolution observations probe a dynamically distinct upper atmospheric region, rather than the deeper jet forming layers.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: With an increased focus on the observing and modelling of mini-Neptunes, there comes a need to better understand the tools we use to model their atmospheres. In this paper, we present the protocol for the CAMEMBERT (Comparing Atmospheric Models of Extrasolar Mini-neptunes Building and Envisioning Retrievals and Transits) project, an intercomparison of general circulation models (GCMs) used by the exoplanetary science community to simulate the atmospheres of mini-Neptunes. We focus on two targets well studied both observationally and theoretically with planned JWST Cycle 1 observations: the warm GJ~1214b and the cooler K2-18b. For each target, we consider a temperature-forced case, a clear sky dual-grey radiative transfer case, and a clear sky multi band radiative transfer case, covering a range of complexities and configurations where we know differences exist between GCMs in the literature. This paper presents all the details necessary to participate in the intercomparison, with the intention of presenting the results in future papers. Currently, there are eight GCMs participating (ExoCAM, Exo-FMS, FMS PCM, Generic PCM, MITgcm, RM-GCM, THOR, and the UM), and membership in the project remains open. Those interested in participating are invited to contact the authors.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $\mu$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$\sigma$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$\sigma$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: Photochemistry is a fundamental process of planetary atmospheres that is integral to habitability, atmospheric composition and stability, and aerosol formation. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Here we show that photochemically produced sulphur dioxide (SO$_2$) is present in the atmosphere of the hot, giant exoplanet WASP-39b, as constrained by data from the JWST Transiting Exoplanet Early Release Science Program and informed by a suite of photochemical models. We find that SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The SO$_2$ distribution computed by the photochemical models robustly explains the 4.05 $\mu$m spectral feature seen in JWST transmission spectra [Rustamkulov et al.(submitted), Alderson et al.(submitted)] and leads to observable features at ultraviolet and thermal infrared wavelengths not available from the current observations. The sensitivity of the SO$_2$ feature to the enrichment of heavy elements in the atmosphere ("metallicity") suggests that it can be used as a powerful tracer of atmospheric properties, with our results implying a metallicity of $\sim$10$\times$ solar for WASP-39b. Through providing improved constraints on bulk metallicity and sulphur abundance, the detection of SO$_2$ opens a new avenue for the investigation of giant-planet formation. Our work demonstrates that sulphur photochemistry may be readily observable for exoplanets with super-solar metallicity and equilibrium temperatures $\gtrsim$750 K. The confirmation of photochemistry through the agreement between theoretical predictions and observational data is pivotal for further atmospheric characterisation studies.
Peer Review Status:Awaiting Review