分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: Two novel benzimidazole-attached spiro[benzofluorene] derivatives, 2,20-(spiro[benzo[c]fluorine-7,90- fluorene]-5,9-diylbis(4,1-phenylene))bis(1-phenyl-1H-benzo[d]imidazole) and 2,20 -(spiro[benzo-[de] anthracene-7,90 -fluorene]-20 ,3-diylbis(4,1-phenylene))bis(1-phenyl-1H-benzo[d]imidazole), were pre- pared by a Suzuki coupling reaction. Their photophysical and photochemical properties were studied systemically. The fluorescent organic light-emitting diodes were fabricated by using them as the emit- ters, all of them showed strong blue emission. Interestingly, from the benzoanthracene derived com- pound a high color purity was found with Commission de L’Eclairage 1931 chromaticity coordinates of (0.15, 0.10) and an efficiency of 1.96 cd/A. To the best of our knowledge, this is the first time to obtain a deep-blue emission with spiro[benzofluorene] derivative in a nondoped device.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: A novel non-conjugated small-molecule electrolyte was invented as a cathode interlayer in PTB7:PC71BM- based polymer solar cells (PSCs). We discovered a significant synergy effect for improving the device efficiency between methanol treatment and the interlayer. The methanol treatment mainly contributed to the open-circuit voltage, while the interlayer primarily enhanced the short-circuit current and fill factor. Under the effective synergy effect, power conversion efficiencies (PCEs) of PTB7:PC71BM-based PSCs were largely improved from 3.89% to 9.79% for conventional PSCs and from 7.34% to 9.10% for inverted PSCs. Our findings create a new path of interfacial modification for highly efficient PSCs.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: An improved concentration of phosphorescent dopant for highly-efficient hybrid white organic light- emitting diodes based on a high radiative exciton ratio (80%) deep-blue emitter has been developed. The high radiative exciton ratio for the deep-blue emitter was found to be the transfer from the higher triplet (T5) to the lowest singlet state (S1) by a “hot-exciton” process. Notably, when the concentration of Ir(2- phq)3 is up to 0.9 wt%, the OLED still exhibited white emission with a maximum total EQE, CE and PE of 22.3%, 53.7 cd A 1 and 60.2 lm W 1, respectively. The exciton transfer mechanism in a high concentration of phosphorescent dopant was also discussed. The studies provide a way to obtain high performance F/P hybrid WOLEDs with a simple architecture and improved doping concentration.