分类： 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间： 2017-05-02
Xu, W [Xu, Wei][ 1,2 ]
Xu, QS [Xu, Qingsong][ 1 ]
Huang, QJ [Huang, Qijin][ 1 ]
Tan, RQ [Tan, Ruiqin][ 3 ]
Shen, WF [Shen, Wenfeng][ 1 ]
Song, WJ [Song, Weijie][ 1,2 ]
摘要： The flexible transparent conductive films (FTCFs) of silver nanowire-polyethylene terephthalate (AgNW- PET) were prepared by a facile method including vacuum filtration and mold transferring. The effect of silver nanowire weight density on the optical and electrical properties of films, as well as the electrical percolation was investigated. The obtained typical AgNW-PET film exhibited high figure of merit of 31.3 × 10−3 Ω−1 with low sheet resistance of 4.95 Ω sq−1 and high transparency at 550 nm of 83.0% (ex- cluding PET substrate). The resulting FTCFs based on PET substrate with high transmittance and low sheet resistance have a great potential in the application of high-performance flexible electronics and photo- voltaic devices.
分类： 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间： 2017-05-02
Huang, QJ [Huang, Qijin][ 1 ]
Shen, WF [Shen, Wenfeng][ 1 ]
Xu, QS [Xu, Qingsong][ 1 ]
Tan, RQ [Tan, Ruiqin][ 2 ]
Song, WJ [Song, Weijie][ 1 ]
摘要： Silver nanoparticles with a mean diameter of approximately 30 nm were synthesized by reduction of silver nitrate with triethanolamine in the presence of polyacrylic acid. Silver nanoparticle-based ink was prepared by dispersing silver nanoparticles into a mixture of water and ethylene glycol. The mechanism for the dispersion and aggregation of silver nanoparticles in ink is discussed. The strong electrostatic repulsions of the carboxylate anions of the adsorbed polyacrylic acid molecules disturbed the aggrega- tion of metal particles in solutions with a high pH value (pH > 5). An inkjet printer was used to deposit this silver nanoparticle-based ink to form silver patterns on photo paper. The actual printing qualities of the silver tracks were then analyzed by variation of printing passes, sintering temperature and time. The results showed that sintering temperature and time are associated strongly with the conductivity of the inkjet-printed conductive patterns. The conductivity of printed patterns sintered at 150 C increased to 2.1 107 S m 1, which was approximately one third that of bulk silver. In addition, silver tracks on paper substrate also showed better electrical performance after folding. This study demonstrated that the resulting ink-jet printed patterns can be used as conductive tracks in flexible electronic devices.
分类： 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间： 2017-05-02
Xu, QS [Xu, Qingsong][ 1 ]
Shen, WF [Shen, Wenfeng][ 1 ]
Huang, QJ [Huang, Qijin][ 1 ]
Yang, Y [Yang, Ye][ 1 ]
Tan, RQ [Tan, Ruiqin][ 2 ]
Zhu, K [Zhu, Ke][ 1 ]
Dai, N [Dai, Ning][ 3 ]
Song, WJ [Song, Weijie][ 1 ]
摘要： Hybrid transparent conductive films (TCFs) with a sandwich structure composed of aluminum-doped zinc oxide (AZO) and Ag nanowires (AgNWs) were deposited on polyethylene terephthalate (PET) substrates. The AZO layers were prepared at room temperature by RF magnetron sputtering. The AgNWs were synthesized by a modified polyol method and inserted into the AZO layers. The optical properties and conductivity can be modified by the number of spin-coating cycles of an AgNWs suspension. Typically, an AZO/AgNW/AZO hybrid film exhibited an optical transmittance of 80.5%, a sheet resistance of 27.6 U sq 1 and an optical haze of 14.9%. The increase in optical haze caused by the silver nanowires may be beneficial for applications in solar cells. The hybrid films presented excellent flexible stability, showing only minor resistance changes and no surface cracks compared with pure AZO films. The AZO layers acted as the protecting layers that enhanced the adhesive and thermal stability of the hybrid films. The resulting hybrid TCFs with an AZO/ AgNW/AZO sandwich structure show potential applications in flexible electronics, energy storage and photovoltaic devices.
分类： 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间： 2017-05-02
Shen, WF [Shen, Wenfeng][ 1 ]
Zhang, XP [Zhang, Xianpeng][ 1 ]
Huang, QJ [Huang, Qijin][ 1 ]
Xu, QS [Xu, Qingsong][ 1 ]
Song, WJ [Song, Weijie][ 1 ]
摘要： Silver nanoparticles (NPs) which could be kept in solid form and were easily stored without degeneration or oxidation at room temperature for a long period of time were synthesized by a simple and environmentally friendly wet chemistry method in an aqueous phase. Highly stable dispersions of aqueous silver NP inks, sintered at room temperature, for printing highly conductive tracks ($8.0 mU cm) were prepared simply by dispersing the synthesized silver NP powder in water. These inks are stable, fairly homogeneous and suitable for a wide range of patterning techniques. The inks were successfully printed on paper and polyethylene terephthalate (PET) substrates using a common color printer. Upon annealing at 180 C, the resistivity of the printed silver patterns decreased to 3.7 mU cm, which is close to twice that of bulk silver. Various factors affecting the resistivity of the printed silver patterns, such as annealing temperature and the number of printing cycles, were investigated. The resulting high conductivity of the printed silver patterns reached over 20% of the bulk silver value under ambient conditions, which enabled the fabrication of flexible electronic devices, as demonstrated by the inkjet printing of conductive circuits of LED devices.
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