分类: 物理学 >> 凝聚态:结构、力学和热性能 提交时间: 2024-06-04
摘要: The expanding applications call for novel new-generation wide-bandgap semiconductors. Here, we show that a compound only composed of the ordinary elements Na and Cl, namely three-dimensional NaCl2 crystal, is a wide-bandgap semiconductor. This finding benefits from the breaking of conventional stoichiometry frameworks in the theoretical design, leading to the discovery of three-dimensional XY2 (X = Na, Li, K; Y = Cl, F, Br, I) crystals, with covalent bonds of Y pairs inducing the wide bandgap from 2.24 to 4.45 eV. Crucially, such an unexpected NaCl2 crystal was successfully synthesized under ambient conditions. The unconventional stoichiometric strategy with other chemical elements potentially yields more wide-bandgap semiconductors, offering the capability for bandgap tuning. These unconventional stoichiometric materials may also exhibit superconductivity, transparent inorganic electrides, high-energy-density, and beyond.
分类: 光学 >> 量子光学 提交时间: 2023-02-24
摘要: Benefitting from the excellent characteristics such as low cytotoxicity, functionalization versatility, and tunable fluorescence, nanodiamonds (NDs) have shown enormous application potentials in the biomedical field. Herein, we proposed, for the first time to our best knowledge, to integrate NDs on a plasmonic interface constructed on a side-polished fiber using drop-casting method. The added NDs engineers the plasmonic interface towards improving the sensing field, thus enhancing the sensitivity, which, moreover, is significantly dependent on the number of drop-casting cycles (DCs) and the used concentration of NDs dispersion solution. Experimental results suggest that properly increasing the NDs dispersion concentration is beneficial to obtain a higher sensitivity while using a fewer number of DCs, but the excessive concentration extremely deteriorates the resonance dip. Experimentally, using the optimal 0.2 mg/mL concentration and 3 DCs, we achieve the highest RI sensitivity of 3582 nm/RIU, which shows an enhancement of 73.8% compared to the case without NDs modification. The sensitivity enhancement in biosensing is also proved by employing bovine serum albumin as a demo. The behind mechanism is explored via characterizations and simulations. This work opens up a new application form for NDs, i.e. integrating NDs with a plasmonic interface towards high-performance biosensing.
分类: 天文学 >> 天文学 提交时间: 2023-02-19
摘要: Close encounters between young stellar objects in star forming clusters are expected to dramatically perturb circumstellar disks. Such events are witnessed in numerical simulations of star formation, but few direct observations of ongoing encounters have been made. Here we report sub-0".1 resolution Atacama Large Millimeter Array (ALMA) and Jansky Very Large Array (JVLA) observations towards the million year old binary protostar Z CMa in dust continuum and molecular line emission. A point source ~4700 au from the binary has been discovered at both millimeter and centimeter wavelengths. It is located along the extension of a ~2000 au streamer structure previously found in scattered light imaging, whose counterpart in dust and gas emission is also newly identified. Comparison with simulations shows signposts of a rare flyby event in action. Z CMa is a "double burster", as both binary components undergo accretion outbursts, which may be facilitated by perturbations to the host disk by flybys.
分类: 天文学 >> 天文学 提交时间: 2023-02-19
摘要: EX Lup is a low-mass pre-main sequence star that occasionally shows accretion-related outbursts. Here, we present JWST/MIRI medium resolution spectroscopy obtained for EX Lup fourteen years after its powerful outburst. EX Lup is now in quiescence and displays a Class II spectrum. We detect a forest of emission lines from molecules previously identified in infrared spectra of classical T Tauri disks: H2O, OH, H2, HCN, C2H2, and CO2. The detection of organic molecules demonstrates that they are back after disappearing during the large outburst. Spectral lines from water and OH are for the first time de-blended and will provide a much improved characterization of their distribution and density in the inner disk. The spectrum also shows broad emission bands from warm, sub-micron size amorphous silicate grains at 10 and 18 um. During the outburst, in 2008, crystalline forsterite grains were annealed in the inner disk within 1 au, but their spectral signatures in the 10 um silicate band later disappeared. With JWST we re-discovered these crystals via their 19.0, 20.0, and 23.5 um emission, whose strength implies that the particles are at ~3 au from the star. This suggests that crystalline grains formed in 2008 were transported outwards and now approach the water snowline, where they may be incorporated into planetesimals. Containing several key tracers of planetesimal and planet formation, EX Lup is an ideal laboratory to study the effects of variable luminosity on the planet-forming material and may provide explanation for the observed high crystalline fraction in solar system comets.
分类: 光学 >> 量子光学 提交时间: 2023-02-19
摘要: Owing to the unique electronic spin properties, the nitrogen-vacancy (NV) centers hosted in diamond have emerged as a powerful quantum sensor for various physical parameters and biological species. In this work, a miniature optical-fiber quantum probe, configured by chemically-modifying nanodiamonds NV centers on the surface of a cone fiber tip, is developed. Based on continue-wave optically detected magnetic resonance method and lock-in amplifying technique, it is found that the sensing performance of the probe can be engineered by varying the nanodiamonds dispersion concentration and modification duration in the chemical modification process. Combined with a pair of magnetic flux concentrators, the magnetic field detection sensitivity of the probe is significantly enhanced to 0.57 nT/Hz1/2 @ 1Hz, a new record among the fiber magnetometers based on nanodiamonds NV. Taking Gd3+ as the demo, the capability of the probe in paramagnetic species detection is also demonstrated experimentally. Our work provides a new approach to develop NV center as quantum probe featuring high integration, miniature size, multifunction, and high sensitivity, etc.