分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-04-06
摘要: The bio-based diamine and epoxy monomer derived from isosorbide are synthesized. Especially, the diamine is obtained using microwave assistant thiol-ene coupling reaction in the aqueous media and the influence of reaction parameters, such as initiator con
分类: 材料科学 >> 材料科学(综合) 提交时间: 2017-03-30
摘要: The bio-based diamine and epoxy monomer derived from isosorbide are synthesized. Especially, the diamine is obtained using microwave assistant thiol-ene coupling reaction in the aqueous media and the influence of reaction parameters, such as initiator con
分类: 材料科学 >> 材料科学(综合) 提交时间: 2017-03-30
摘要: The bio-based diamine and epoxy monomer derived from isosorbide are synthesized. Especially, the diamine is obtained using microwave assistant thiol-ene coupling reaction in the aqueous media and the influence of reaction parameters, such as initiator con
分类: 其他 >> 综合 提交时间: 2023-03-12 合作期刊: 《Art & Design Research》
摘要: Since western oil painting was introduced into China, Chinese painters began to explore the nationalization of oil painting. The current development trend of Chinese oil painting is based on local culture to explore the fusion of Chinese culture and western oil painting. My oil painting landscape creation absorbs and draws lessons from the philosophy of Chinese painting, the scattershot perspective and the beauty of the artistic conception, and tries to explore the style of Chinese landscape painting with national characteristics, by interpreting the connotation of my oil painting creation, exploring the national tendency in my landscape oil painting creation, better promoting the innovation and development of Chinese oil painting.
分类: 核科学技术 >> 辐射物理与技术 提交时间: 2024-06-07
摘要: 本文介绍了一种超疏水性三聚氰胺(ME)海绵(ME-g-PLMA),该海绵通过高能辐射诱导的原位共价接枝长烷基十二烷基甲基丙烯酸酯(LMA)到ME海绵上,以实现高效的油水分离。所得的ME-g-PLMA海绵具有优良的孔隙结构,具有超疏水性(水接触角为154°)和超亲油性,可吸收高达自身重量66-168倍的各类油脂。所得到的ME-g-PLMA海绵可以通过连接泵连续分离水面上的浮油,或者通过重力驱动装置分离水下的浮油。ME-g-PLMA海绵在长期浸泡在不同的腐蚀性溶液中,多次反复吸油后,也能保持其高疏水性。所得改性ME-g-PLMA海绵具有优异的分离性能,在溢油清理方面具有巨大的潜力。
提交时间: 2017-05-02
摘要: Under seawater superoleophobic polyvinylidene fluoride [PVDF] membrane inspired by mussel is successfully fabricated for both surfactant-free and surfactant-stabilized oil/seawater separation. The conventional PVDF membrane is modified by a simple solutio
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: A series of bio-based unsaturated polyesters was synthesized by melt polycondensation of itaconic acid with 1,4-butanediol and glycerol. Their chemical structures were confirmed by FT-IR, 1H NMR, acid and hydroxyl values. Waterborne UV curable dispersion coatings based on these polyesters and acrylated epoxidized soybean oil (AESO) were formulated. The average particle size and their stability before curing as well as the coating properties after curing, including adhesion, flexibility, pencil hardness and solvent resistance, were investigated. Results demonstrated that the glycerol segment in the polyesters together with AESO led to the excellent coating properties in terms of highest grade of adhesion (5B), 0T flexibility, pencil hardness of 5H and excellent solvent resistance (no appearance change after 250 double rubs with ethanol and acetone). This work provided us the coating systems combining the merits of being bio-based, UV-curable and water dispersible.vv
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: In this paper, stainless steel meshes with super-hydrophobic and superoleophilic surfaces were fabricated by rapid and simple one-step immersion in a solution containing hydrochloric acid and stearic acid. The apparent contact angles were tested by a video contact angle measurement system (CA). Field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectrosco-py (FTIR), and X-ray photoelectron spectroscopy (XPS) were conducted to characterize the surface topographies and chemical compositions. The SEM results showed that mesh surfaces were covered by ferric stearate (Fe[CH3(CH2)16COO]2) with low surface energy. The CA test results showed that the mesh had a maximum apparent contact angle of 160 ± 1.0° and a sliding angle of less than 5.0°for the water droplet, whereas the apparent contact angle for the oil droplet was zero. Ultrasound oscillation and exposure tests at atmospheric conditions and immersion tests in 3.5 wt % NaCl aqueous solution were conducted to confirm the mesh with excellent superhydrophobic and superoleophilic properties. On the basis of the superhydrophobic mesh, a miniature separation device pump was designed to collect pure oil from the oil/water mixture. It showed that the device was easier and convenient. The techniques and materials presented in this work are promising for application to wastewater and oil spill treatment.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: A biobased monofunctional compatibilizer (called Epicard) is first synthesized by the reaction of cardanol with epichlorohydrin as confirmed by Fourier transform infrared and 1H NMR. Subsequently, biosourced polymers, polylactide (PLA) and starch, are melt-blended by a twin-screw extruder with Epicard. Confirmed by the measurements of contact angle and 1H nuclear magnetic resonance of the extracted starches from PLA/starch/Epicard blends, the Epicard only possesses a monoepoxy group to mainly react with starch and then increased the hydrophobicity of the starches during the melt-blending process. As a result, an obvious improvement to the interfacial adhesion between starch and PLA is observed by the scanning electron microscopy. Furthermore, the tensile properties of PLA/starch blends are effectively improved with the addition of Epicard. This study suggests a simple but effective material technique by utilizing a novel plant oil modifier to increase interfacial adhesion in fabricating fully biobased PLA/starch blends with superior tensile properties.
分类: 生物学 >> 植物学 >> 应用植物学 提交时间: 2016-05-04
摘要: The widespread production of cash crops can result in the decline of forests, peatlands, rice fields and local community land. Such unwanted land-use and land-cover (LULC) change can lead to decreased carbon stocks, diminished biodiversity, displaced communities and reduced local food production. In this study, we analysed to what extent four main commodities, namely, palm oil, pulpwood, rice and rubber, can be produced in North and East Kalimantan in Indonesia without such unwanted LULC change. We investigated the technical potential of four measures to mitigate unwanted LULC change between 2008 and 2020 under low, medium and high scenarios, referring to the intensities of the mitigation measures compared with those implemented in 2008. These measures are related to land sparing through (i) the improvements of yields, (ii) chain efficiencies, (iii) chain integration and (iv) the steering of any expansion of these commodities to suitable and available underutilised (potentially degraded) lands. Our analyses resulted in a land-sparing potential of 0.4–1.2 Mha (i.e. 24–62% of the total land demand of the commodities) between 2008 and 2020, depending on the land-use projection of the four commodities and the scenario for implementing the mitigation measures. Additional expansion on underutilised land is the most important mitigation measure (45–62% of the total potential), followed by yield improvements as the second most important mitigation measure (32–46% of the total potential). Our study shows that reconciling the production of palm oil, pulpwood, rice and rubber with the maintenance of existing agricultural lands, forests and peatlands is technically possible only (i) under a scenario of limited agricultural expansion, (ii) if responsible land zoning is applied and enforced and (iii) if the yields and chain efficiencies are strongly improved.