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  • Assessment of organic compost and biochar in promoting phytoremediation of crude-oil contaminated soil using Calendula officinalis in the Loess Plateau, China

    分类: 地球科学 >> 地理学 提交时间: 2021-07-23 合作期刊: 《干旱区科学》

    摘要: The Loess Plateau, located in Gansu Province, is an important energy base in China because most of the oil and gas resources are distributed in Gansu Province. In the last 40 a, ecological environment in this region has been extremely destroyed due to the over-exploitation of crude-oil resources. Remediation of crude-oil contaminated soil in this area remains to be a challenging task. In this study, in order to elucidate the effects of organic compost and biochar on phytoremediation of crude-oil contaminated soil (20 g/kg) by Calendula officinalis, we designed five treatments, i.e., natural attenuation (CK), planted C. officinalis only (P), planted C. officinalis with biochar amendment (PB), planted C. officinalis with organic compost amendment (PC), and planted C. officinalis with co-amendment of biochar and organic compost (PBC). After 152 d of cultivation, total petroleum hydrocarbons (TPH) removal rates of CK, P, PB, PC and PBC were 6.36%, 50.08%, 39.58%, 73.10% and 59.87%, respectively. Shoot and root dry weights of C. officinalis significantly increased by 172.31% and 80.96% under PC and 311.61% and 145.43% under PBC, respectively as compared with P (P<0.05). Total chlorophyll contents in leaves of C. officinalis under P, PC and PBC significantly increased by 77.36%, 125.50% and 79.80%, respectively (P<0.05) as compared with PB. Physical-chemical characteristics and enzymatic activity of soil in different treatments were also assessed. The highest total N, total P, available N, available P and SOM (soil organic matter) occurred in PC, followed by PBC (P<0.05). C. officinalis rhizospheric soil dehydrogenase (DHA) and polyphenol oxidase (PPO) activities in PB were lower than those of other treatments (P<0.05). The values of ACE (abundance-based coverage estimators) and Chao 1 indices for rhizospheric bacteria were the highest under PC followed by PBC, P, PB and CK (P<0.05). However, the Shannon index for bacteria was the highest under PC and PBC, followed by P, PB and CK (P<0.05). In terms of soil microbial community composition, Proteiniphilum, Immundisolibacteraceae and Solimonadaceae were relatively more abundant under PC and PBC. Relative abundances of Pseudallescheria, Ochroconis, Fusarium, Sarocladium, Podospora, Apodus, Pyrenochaetopsis and Schizothecium under PC and PBC were higher, while relative abundances of Gliomastix, Aspergillus and Alternaria were lower under PC and PBC. As per the nonmetric multidimensional scaling (NMDS) analysis, application of organic compost significantly promoted soil N and P contents, shoot length, root vitality, chlorophyll ratio, total chlorophyll, abundance and diversity of rhizospheric soil microbial community in C. officinalis. A high pH value and lower soil N and P contents induced by biochar, altered C. officinalis rhizospheric soil microbial community composition, which might have restrained its phytoremediation efficiency. The results suggest that organic compost-assisted C. officinalis phytoremediation for crude-oil contaminated soil was highly effective in the Loess Plateau, China.

  • Measurement of the Br(n,gamma) cross sections up to stellar s-process temperatures at the CSNS Back-n

    分类: 物理学 >> 核物理学 分类: 物理学 >> 地球物理学、天文学和天体物理学 提交时间: 2023-09-12

    摘要: The neutron capture cross sections (${n, upgamma}$) of Bromine was performed with the time-of-flight (TOF) technique at the Back-n facility of the China Spallation Neutron Source (CSNS). Prompt $ upgamma$-rays originating from neutron-induced capture events were detected by four C${}_6$D${}_6$ detectors. The pulse height weighting technique (PHWT) and the double-bunch unfolding method based on the Bayesian theory were used in the data analysis. To obtain reliable measurement results, background deductions, normalization, and corrections were carefully considered. The multilevel R-matrix Bayesian code SAMMY was used to extract the resonance parameters in the resolved resonance region (RRR). The average cross sections in unresolved resonance region the was obtained from 10 to 400 keV. The experimental results were compared with the data of several evaluated libraries and previous experiments in the resolved and unresolved resonance region. The TALYS code was used to describe the average cross sections in the unresolved resonance region. Astrophysical Maxwell average cross sections (MACSs) of ${}^{79,81}$Br from $ kT $ = 5 to 100 keV was calculated over a sufficiently wide range of neutron energies. At a thermal energy of $kT=30$ keV, the MACS value for ${}^{79}$Br 638$ pm$64 mb is in good agreement with the KADoNiS recommended value. By contrast, the value of 293$ pm$29 mb for ${}^{81}$Br is substantially higher than those of the evaluated database and the KADoNiS recommended value.