分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: Ordered tungsten and aluminum co-doped mesoporous KIT-6 catalysts (W-Al-KIT-6) with different Si/Al molar ratios were successfully synthesized by a one-pot synthesis method. The obtained W-Al-KIT-6 catalysts were tested for catalytic conversion of 1-butene and ethene to propene via isomerization of 1-butene to 2-butene and subsequent cross metathesis of 2-butene and ethene. Various characterization techniques, such as ICP-OES, XRD, BET, TEM, Raman, XPS and NH3-TPD, were used to characterize the catalysts. The introduction of Al did not change the mesoporous structure of KIT-6 when the nominal Si/Al was 10, 20 or 30. Moreover, the sample demonstrated a larger amount of acidic sites. The W-Al-KIT-6 catalysts with suitable Si/Al ratios illustrated a superior catalytic performance to W-KIT-6 catalyst. The origin of catalytic performance enhancement over W-Al-KIT-6 catalysts is preliminarily discussed and ascribed to the highly disperse W species and a large amount of acidic sites. The acidic sites were formed by the introduction of a suitable amount of Al in the W-KIT-6 framework, which accelerated the isomerization of 1-butene to 2-butene and promoted the cross metathesis of 2-butene and ethene to propene.
提交时间: 2017-05-02
摘要: Intermediate tin oxide [Sn3O4] crystals have been successfully synthesized through a simple one-pot hydrothermal route by employing SnCl2 center dot 2H[2]O and NaOH as raw materials. The crystmlline structure, morphology and optical properties of Sn3O4 ma
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-08
摘要: Tungsten substituted mesoporous FDU-12 (W-FDU-12) catalysts were synthesized by a one-pot hydrothermal process using F127 as the structure directing agent. The studies of TEM, SAXS and BET illustrated that the highly ordered mesoporous structure of FDU-12 was maintained in the doped W-FDU-12 samples. XPS studies revealed that a high concentration of W5+ species appeared in doped W-FDU-12 catalysts whereas supported WO3/FDU-12 and WO3/SiO2 catalysts only contained W6+ species. Tandem catalytic conversion of 1-butene and ethene to propene through isomerization of 1-butene to 2-butene and consecutive cross metathesis of 2-butene and ethene in a fixed-bed reactor at different temperatures and atmospheric pressure was used to evaluate the catalytic performance of the W-FDU-12 catalyst, combined with MgO. The catalytic results showed that the doped W-FDU-12 illustrated a superior catalytic performance relative to the supported WO3/FDU-12 and WO3/SiO2 catalysts. The higher metathesis activity of W-FDU-12 catalysts can be ascribed to the good dispersion of W species and the incorporation of W species into the framework of FDU-12, forming a substantial amount of W5+, which was beneficial for the cross metathesis of 2-butene and ethene to propene.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: The flexible transparent conductive films (FTCFs) of silver nanowire-polyethylene terephthalate (AgNW- PET) were prepared by a facile method including vacuum filtration and mold transferring. The effect of silver nanowire weight density on the optical and electrical properties of films, as well as the electrical percolation was investigated. The obtained typical AgNW-PET film exhibited high figure of merit of 31.3 × 10−3 Ω−1 with low sheet resistance of 4.95 Ω sq−1 and high transparency at 550 nm of 83.0% (ex- cluding PET substrate). The resulting FTCFs based on PET substrate with high transmittance and low sheet resistance have a great potential in the application of high-performance flexible electronics and photo- voltaic devices.
分类: 天文学 >> 天体物理学 提交时间: 2024-05-20
摘要: Context : Understanding the mechanisms that launch and shape powerful relativistic jets from supermassive black holes (SMBHs) in high-redshift active galactic nuclei (AGN) is crucial for probing the co-evolution of SMBHs and galaxies over cosmic time. Aims :We study the high-redshift ($z=3.396$) blazar OH~471 to explore the jet launching mechanism in the early Universe. Methods : Using multi-frequency radio monitoring observations and high-resolution Very Long Baseline Interferometry imaging over three decades, we study the milliarcsecond structure and long-term variability of OH~471. Results : Spectral modelling of the radio flux densities reveals a synchrotron self-absorbed spectrum indicating strong magnetic fields within the compact core. By applying the flux freezing approximation, we estimate the magnetic flux carried by the jet and find that it reaches or exceeds theoretical predictions for jets powered by black hole spin energy via the Blandford-Znajek mechanism. This implies that OH~471 was in a magnetically arrested disk (MAD) state where the magnetic flux accumulated near the horizon regulates the accretion flow, allowing efficient extraction of black hole rotational energy. Conclusions : Our study demonstrates the dominance of MAD accretion in powering the prominent radio flares and relativistic jets observed in the radio-loud AGN OH~471 and statistical studies of large samples of high-redshift AGN will shed light on the role of MAD accretion in launching and accelerating the earliest relativistic jets.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-08
摘要: Highly flexible and transparent film heaters (TFHs) with superior mechanical and thermal stability were fabricated by embedding silver nanowires (AgNWs) into transparent polyimide (PI) films using a solution coating method. The fabricated AgNW/PI hybrid TFHs exhibited higher heating temperatures ($96 C) with lower input voltage ($6 V), shorter response time (T < 40 s), and lower power consumption (160.6 C cm2 W 1) than ITO/FTO heaters, as well as stability after repeated use. The AgNW/PI hybrid TFHs also showed excellent resistance to bending. After undergoing outer bending for a 1000 times, the change of sheet resistance was less than 18%. The effective embedment of the AgNW network in the surface of the transparent PI film not only decreased the surface roughness (Rrms < 1 nm) but also enhanced the resistance against oxidation and moisture. Potential applications of the AgNW/PI TFHs in window defogging and thermochromics are demonstrated.
提交时间: 2017-05-02
摘要: Heterovalent Sn2O3 nanosheets were fabricated via an oxidation annealing process and the formation mechanism was investigated. The temperature required to complete the phase transformation from Sn3O4 to Sn2O3 was considered. Two contrasting experiments sh
分类: 天文学 >> 天文学 提交时间: 2023-02-19
摘要: The D-Egg, an acronym for ``Dual optical sensors in an Ellipsoid Glass for Gen2,'' is one of the optical modules designed for future extensions of the IceCube experiment at the South Pole. The D-Egg has an elongated-sphere shape to maximize the photon-sensitive effective area while maintaining a narrow diameter to reduce the cost and the time needed for drilling of the deployment holes in the glacial ice for the optical modules at depths up to 2700 meters. The D-Egg design is utilized for the IceCube Upgrade, the next stage of the IceCube project also known as IceCube-Gen2 Phase 1, where nearly half of the optical sensors to be deployed are D-Eggs. With two 8-inch high-quantum efficiency photomultiplier tubes (PMTs) per module, D-Eggs offer an increased effective area while retaining the successful design of the IceCube digital optical module (DOM). The convolution of the wavelength-dependent effective area and the Cherenkov emission spectrum provides an effective photodetection sensitivity that is 2.8 times larger than that of IceCube DOMs. The signal of each of the two PMTs is digitized using ultra-low-power 14-bit analog-to-digital converters with a sampling frequency of 240 MSPS, enabling a flexible event triggering, as well as seamless and lossless event recording of single-photon signals to multi-photons exceeding 200 photoelectrons within 10 nanoseconds. Mass production of D-Eggs has been completed, with 277 out of the 310 D-Eggs produced to be used in the IceCube Upgrade. In this paper, we report the des\ ign of the D-Eggs, as well as the sensitivity and the single to multi-photon detection performance of mass-produced D-Eggs measured in a laboratory using the built-in data acquisition system in each D-Egg optical sensor module.
分类: 天文学 >> 天文学 提交时间: 2023-02-19
摘要: IceCube, a cubic-kilometer array of optical sensors built to detect atmospheric and astrophysical neutrinos between 1 GeV and 1 PeV, is deployed 1.45 km to 2.45 km below the surface of the ice sheet at the South Pole. The classification and reconstruction of events from the in-ice detectors play a central role in the analysis of data from IceCube. Reconstructing and classifying events is a challenge due to the irregular detector geometry, inhomogeneous scattering and absorption of light in the ice and, below 100 GeV, the relatively low number of signal photons produced per event. To address this challenge, it is possible to represent IceCube events as point cloud graphs and use a Graph Neural Network (GNN) as the classification and reconstruction method. The GNN is capable of distinguishing neutrino events from cosmic-ray backgrounds, classifying different neutrino event types, and reconstructing the deposited energy, direction and interaction vertex. Based on simulation, we provide a comparison in the 1-100 GeV energy range to the current state-of-the-art maximum likelihood techniques used in current IceCube analyses, including the effects of known systematic uncertainties. For neutrino event classification, the GNN increases the signal efficiency by 18% at a fixed false positive rate (FPR), compared to current IceCube methods. Alternatively, the GNN offers a reduction of the FPR by over a factor 8 (to below half a percent) at a fixed signal efficiency. For the reconstruction of energy, direction, and interaction vertex, the resolution improves by an average of 13%-20% compared to current maximum likelihood techniques in the energy range of 1-30 GeV. The GNN, when run on a GPU, is capable of processing IceCube events at a rate nearly double of the median IceCube trigger rate of 2.7 kHz, which opens the possibility of using low energy neutrinos in online searches for transient events.
分类: 天文学 >> 天文学 提交时间: 2023-02-19
摘要: We report three searches for high energy neutrino emission from astrophysical objects using data recorded with IceCube between 2011 and 2020. Improvements over previous work include new neutrino reconstruction and data calibration methods. In one search, the positions of 110 a priori selected gamma-ray sources were analyzed individually for a possible surplus of neutrinos over atmospheric and cosmic background expectations. We found an excess of $79_{-20}^{+22}$ neutrinos associated with the nearby active galaxy NGC 1068 at a significance of 4.2$\,\sigma$. The excess, which is spatially consistent with the direction of the strongest clustering of neutrinos in the Northern Sky, is interpreted as direct evidence of TeV neutrino emission from a nearby active galaxy. The inferred flux exceeds the potential TeV gamma-ray flux by at least one order of magnitude.