Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: Cyanamide (NH2CN) and its isomer, carbodiimide (HNCNH), may form adenine in the interstellar medium (ISM) via a series of reactions. Therefore, they are considered key prebiotic molecules in the study of the origin of life. We used the three-phase NAUTILUS chemical code, which includes the gas, the dust surface, and the icy mantle, to investigate the formation and destruction of cyanamide and carbodiimide. We added over 200 new chemical reactions of the two isomers and related species, and established a relatively complete network. We applied cold core, hot corino/core and shock models to simulate the different physical environments, and found that the two isomers are mainly produced by the free radical reactions on grain surfaces. Our simulated results suggest that cyanamide and carbodiimide molecules come from surface chemistry at early evolutionary stages. Then they are released back to the gas phase, either by thermal process (in hot cores, hot corinos) or shock-induced desorption (in shock regions).We speculate that it is an inefficient route to form a tautomer of adenine by starting from molecules cyanoacetylene (C3NH), cyanamide and carbodiimide in ISM.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract: We investigated the chemical evolutions of gas phase and grain surface species across the Taurus molecular cloud-1 (TMC-1) filament from translucent phase to dense phase. By comparing observations with modeling results from an up-to-date chemical network, we examined the conversion processes for the carbon-, oxygen-, nitrogen- and sulfur-bearing species, i.e.from their initial atomic form to their main molecular reservoir form both in the gas phase and on the grain surface. The conversion processes were found to depend on the species and A$_V$. The effect of initial carbon to oxygen elemental abundances ratio (C/O) by varying O on the chemistry was explored, and an initial carbon elemental abundance of 2.5 $\times$ 10$^{-4}$ and a C/O ratio of 0.5 could best reproduce the abundances of most observed molecules at TMC-1 CP, where more than 90 molecules have been identified. Based on the TMC-1 condition, we predicted a varied grain ice composition during the evolutions of molecular clouds, with H$_2$O ice as the dominant ice composition at A$_V$ $>$ 4 mag, CO$_2$ ice as the dominant ice composition at A$_V$ $<$ 4 mag, while CO ice severely decreased at A$_V$ around 4--5 mag.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysics submitted time 2023-12-29
Abstract: We studied the unique kinematic properties in massive filament G352.63-1.07 at 1000-AU spatial scale with the dense molecular tracers observed with the Atacama Large Millimeter/submillimeter Array (ALMA). We find the central massive core M1 (12 Msun) being separated from the surrounding filament with a velocity difference of v-v_sys=-2 km/s and a transverse separation within 3 arcsec. Meanwhile, as shown in multiple dense-gas tracers, M1 has a spatial extension closely aligned with the main filament and is connected to the filament towards its both ends. M1 thus represents a very beginning state for a massive young star-forming core escaping from the parental filament, within a time scale of ~4000 years. Based on its kinetic energy (3.5x10^44 erg), the core escape is unlikely solely due to the original filament motion or magnetic field, but requires more energetic events such as a rapid intense anisotropic collapse. The released energy also seems to noticeably increase the environmental turbulence. This may help the filament to become stabilized again.