• A Cross-Laboratory Comparison Study of Titan Haze Analogs: Surface Energy

    分类: 天文学 >> 天文学 提交时间: 2023-02-19

    摘要: In Titan's nitrogen-methane atmosphere, photochemistry leads to the production of complex organic particles, forming Titan's thick haze layers. Laboratory-produced aerosol analogs, or "tholins", are produced in a number of laboratories; however, most previous studies have investigated analogs produced by only one laboratory rather than a systematic, comparative analysis. In this study, we performed a comparative study of an important material property, the surface energy, of seven tholin samples produced in three independent laboratories under a broad range of experimental conditions, and explored their commonalities and differences. All seven tholin samples are found to have high surface energies, and are therefore highly cohesive. Thus, if the surface sediments on Titan are similar to tholins, future missions such as Dragonfly will likely encounter sticky sediments. We also identified a commonality between all the tholin samples: a high dispersive (non-polar) surface energy component of at least 30 mJ/m2. This common property could be shared by the actual haze particles on Titan as well. Given that the most abundant species interacting with the haze on Titan (methane, ethane, and nitrogen) are non-polar in nature, the dispersive surface energy component of the haze particles could be a determinant factor in condensate-haze and haze-lake liquids interactions on Titan. With this common trait of tholin samples, we confirmed the findings of a previous study by Yu et al. (2020) that haze particles are likely good cloud condensation nuclei (CCN) for methane and ethane clouds and would likely be completely wetted by the hydrocarbon lakes on Titan.

  • Families and Clusters of Diffuse Interstellar Bands: a Data-Driven Correlation Analysis

    分类: 天文学 >> 天文学 提交时间: 2023-02-19

    摘要: More than 500 diffuse interstellar bands (DIBs) have been observed in astronomical spectra, and their signatures and correlations in different environments have been studied over the past decades to reveal clues about the nature of the carriers. We compare the equivalent widths of the DIBs, normalized to the amount of reddening, E_B-V, to search for anti-correlated DIB pairs using a data sample containing 54 DIBs measured in 25 sight lines. This data sample covers most of the strong and commonly detected DIBs in the optical region, and the sight lines probe a variety of ISM conditions. We find that 12.9% of the DIB pairs are anti-correlated, and the lowest Pearson correlation coefficient is r_norm ~ -0.7. We revisit correlation-based DIB families and are able to reproduce the assignments of such families for the well-studied DIBs by applying hierarchical agglomerative and k-means clustering algorithms. We visualize the dissimilarities between DIBs, represented by 1 - r_norm, using multi-dimensional scaling (MDS). With this representation, we find that the DIBs form a rather continuous sequence, which implies that some properties of the DIB carriers are changing gradually following this sequence. We also find at that least two factors are needed to properly explain the dissimilarities between DIBs. While the first factor may be interpreted as related to the ionization properties of the DIB carriers, a physical interpretation of the second factor is less clear and may be related to how DIB carriers interact with surrounding interstellar material.