Subjects: Materials Science >> Materials Science (General) submitted time 2023-03-18 Cooperative journals: 《材料研究学报》
Abstract： The La0.6Pr0.4Fe11.4Si1.6B0.2 alloy was produced by using industrial grade raw materials. The phase constituents and thermal magnetic properties of the alloy were characterized by X-ray diffraction with Cu kα radiation and vibration sample magnetism respectively. The influence of hydrogen absorption pressure on magnetocaloric effect and hydrogen desorption process were investigated. Results show that the annealing treated alloy was subjected to hydrogenation at 0.13 and 0.2 MPa, correspondingly its Curie temperature increased to 320 and 321 K respectively. The taking place of dehydrogenation was much easier for the alloy hydrogenated at lower absorption pressure rather than that at higher pressure. The Curie temperature of the alloy hydrogenated at 0.13 MPa and then dehydrogenated at 473K could lower to room temperature range, correpondingly the maximal magnetic entropy of the hydrides decreased while the relative cooling power were increased.
Subjects: Materials Science >> Materials Science (General) submitted time 2023-03-19 Cooperative journals: 《金属学报》
Abstract： Recently, La(Fe, Si)13- based magnetic refrigeration materials have been widely explored due to the advantages of giant magnetocaloric effect (MCE), tunable Curie temperature (TC), low cost of raw materials and excluding deleterious elements compared to other room-temperature giant MCE materials such as Gd5(Ge1-xSix)4, MnFeP0.45As0.55 and MnAs based compounds. In this work, in order to shift the TC to around room temperature and maintain the large MCE, the method of absorbing hydrogen was employed. La0.9Ce0.1Fe11.44Si1.56 hydride was prepared by saturated hydrogen absorption and then hydrogen contents and TC of the hydrides were controlled by subsequent dehydrogenation at different temperatures (Td=200~250 ℃ for 3 h). The phase structure and magnetocaloric effect were investigated. The results show that the samples possess the cubic NaZn13-type structure with a small amount of a-Fe as impurity phase. TC exhibits an approximately linear decrease with increasing the dehydrogenation temperature. The isothermal magnetic entropy change (ΔSm) of the hydrides decreases compared with the parent compound, which is mainly attributed to the fact that the field-induced itinerant-electron metamagnetic transition has been weakened upon hydrogen absorption. For the sample desorbed hydrogen at temperatures above 230 ℃, ΔSm is remarkably decreased and favorably the magnetic hysteresis loss has been reduced simultaneously. With further increasing the temperature to 250 ℃, ΔSm curve is broadened, weakening the characteristic of the firstorder phase transition. Due to the intrinsic brittleness of hydrides, the preparation of a certain shape is of great importance for practical application. For a magnetic field change of 1.5 T, the maximum adiabatic temperature change (ΔTad) and ΔSm for the bonded block of fully hydrogen absorption La0.9Ce0.1Fe11.44Si1.56 hydride are about 2.7 K and 7.5 J/(kg·K), respectively, which are larger than those of La(Fe, Co, Si)13 materials in the same magnetic field change range. In conclusion, the bonded La0.9Ce0.1Fe11.44Si1.56 hydrides with good MCE and different TC have been successfully prepared and will be very useful for the practical application of layered magnetic refrigerants at ambient temperature under low field change in magnetic refrigerators.
Subjects: Materials Science >> Materials Science (General) submitted time 2016-11-10 Cooperative journals: 《金属学报》
Abstract：对La0.9Ce0.1Fe11.44Si1.56合金进行饱和吸氢，之后在不同温度(Td=200~250 ℃)下进行3 h放氢处理，得到H含量不同即具有不同Curie温度(TC)的氢化物，对其相结构和磁热效应进行测试分析。结果表明，合金在吸氢前后有相同的相结构，主相为NaZn13型立方结构，同时含有少量α-Fe杂相；随着放氢温度的提高，TC近似线性的降低；由于H原子的引入消弱了一级巡游电子变磁(IEM)转变，等温磁熵变较母合金有所降低，当Td＞230 ℃时，磁熵变随着放氢温度的升高明显降低，磁滞减小，当Td=250 ℃时，磁熵变曲线宽化，一级相变特性弱化。饱和吸氢后的La0.9Ce0.1Fe11.44Si1.56Hy粉末经固化后得到的粘结样品在0~1.5 T变化的磁场下，绝热温变和等温磁熵变的最大值分别达到2.7 K和7.5 J/(kg?K)。
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