摘要: Perylene tetracarboxylic anhydride (PTCDA) was reacted with 6-aminocaproic acid to form the corresponding perylene bisimide (PBI). PBI was used as the foundation for oligomerisation of glycidol in a ring-opening reaction of glycidol leading to a hyper branched, water-soluble glycidol derivative of perylene (PBI-HPG). PBI-HPG was bound to the reduced graphene oxide via p–p stacking resulting in a compound termed PBI-HPG/RGO. The structure and morphology of PBI-HPG/RGO were investigated by infrared spectroscopy (FT-IR), wide angle X-ray diffractometry (WAXD), transmission electron microscopy (TEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). PBI- HPG/RGO was blended at different loadings in order to improve the thermal and mechanical properties of epoxy composites. The maximum Tg of the epoxy composites was about 20 C and the decomposition temperature (Td) was 26 C higher than that of neat epoxy. The incorporation of PBI- HPG/RGO yields a material with an impact strength of 39.6 kJ m 2 and a tensile strength at 0.7 wt%. It increased by 50.8% and 62.3%, respectively, compared to the neat epoxy.
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期刊:
RSC ADVANCES
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分类:
材料科学
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材料科学(综合)
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引用:
ChinaXiv:201705.00242
(或此版本
ChinaXiv:201705.00242V1)
doi:10.12074/201705.00242
CSTR:32003.36.ChinaXiv.201705.00242.V1
- 推荐引用方式:
Pan, LL [Pan, Lulu][ 1 ],Ban, JF [Ban, Jianfeng][ 3 ],Lu, SR [Lu, Shaorong][ 1 ],Chen, GX [Chen, Guoxin][ 2 ],Yang, J [Yang, Jin][ 1 ],Luo, QY [Luo, Qiyun][ 1 ],Wu, LY [Wu, Linyan][ 1 ],Yu, JH [Yu, Jinhong][ 1,2 ].(2017).Improving thermal and mechanical properties of epoxy composites by using functionalized graphene.RSC ADVANCES.[ChinaXiv:201705.00242]
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